2D Monoelemental Germanene Quantum Dots: Synthesis as Robust Photothermal Agents for Photonic Cancer Nanomedicine

As a new family member of the emerging two‐dimensional (2D) monoelemental materials (Xenes), germanene has shown promising advantages over the prototypical 2D Xenes, such as black phosphorus (BP) and graphene. However, efficient manufacture of novel germanene nanostructures is still a challenge. Herein, a simple top‐down approach for the liquid‐exfoliation of ultra‐small germanene quantum dots (GeQDs) is presented. The prepared GeQDs possess an average lateral size of about 4.5 nm and thickness of about 2.2 nm. The functionalized GeQDs were demonstrated to be robust photothermal agents (PTAs) with outstanding photothermal conversion efficacy (higher than those of graphene and BPQDs), superior stability, and excellent biocompatibility. As a proof‐of‐principle, 2D GeQDs‐based PTAs were used in fluorescence/photoacoustic/photothermal‐imaging‐guided hyperpyrexia ablation of tumors. This work could expand the application of 2D germanene to the field of photonic cancer nanomedicine.     

铁电存储器~(60)Co γ射线及电子总剂量效应研究

以型号为FM28 V100的铁电存储器为研究对象,进行了~(60)Co γ射线和2 Me V电子辐照实验.研究了铁电存储器不同工作方式、不同辐射源下的总剂量辐射损伤规律,用J-750测试部分直流参数和交流参数,分析了存储器敏感参数的变化规律.实验结果表明:对动态、静态加电、静态不加电三种工作方式下的结果进行比较.其中静态加电工作方式下产生的陷阱电荷最多,是存储器最恶劣的工作方式;器件的一些电参数随总剂量发生变化,在功能失效之前部分参数已经失效;在静态加电这种最恶劣的工作方式下,得到~(60)Co γ射线比电子造成更加严重的辐照损伤.     

Effect of microarc oxidation coating on fatigue performance of Ti-Al-Zr alloy

Ceramic coatings of different thickness were fabricated on Ti6Al2Zr1Mo1V alloy by microarc oxidation (MAO), and the effect of the coating on fatigue life was evaluated by 810 Material Test System. The microstructure, phase and chemical composition of the coatings were determined by SEM, XRD and EDS techniques. The coating mainly consists of rutile and a small amount of anatase TiO₂. With oxidation time ranging from 10 to 30 min, the coating thickness increases from 13 to 25 μm, while the interface between coating and substrate becomes more zigzag, characterized by increasing overgrowth regions of coating into substrate. Under the same cyclic stress of 750 MPa, the fatigue life decreases from 2.08 × 10⁶ cycles for uncoated specimen to about 3 × 10⁴ cycles for microarc oxidized specimen. Under the cyclic stress, the thicker the coating, the more cracks initiate in the overgrowth regions of coating into substrate near the interface, which are considered as the notch sites of stress concentration to induce the crack initiation, also is the key factor to cause the facture.     

MIMO量子信道的空间自由度研究

量子通信是一个量子密钥分发过程,目前采用的通信技术严重制约了量子密钥分发的比特率.将多输入多输出（MIMO）技术应用于量子通信系统,提高量子密钥分发的比特率,促进量子通信向高速大容量发展.然而,量子场本身不可避免地存在量子噪声约束容量的增长,限制了可利用空间资源,即空间自由度.文中采用光子场的量子化和满足Schrdinger方程条件的电磁场波动方程推导出MIMO量子信道的空间自由度上限,为开发稳健的MIMO量子通信空时处理算法和优化设计高性能MIMO量子通信系统提供理论基础和技术支持. 关键词： 多输入多输出 量子密钥分发 Schrdinger方程 光子场的量子化     

双空位缺陷石墨纳米带的电子结构和输运性质研究

基于第一原理电子结构和输运性质计算,研究了585双空位拓扑缺陷对锯齿（zigzag）型石墨纳米带（具有椅型（armchair）边）电子结构和输运性质的影响.研究发现,585双空位缺陷的存在使得锯齿型石墨纳米带的能隙增大,并在能隙中出现了一条局域于缺陷处的缺陷态能带,双空位缺陷的取向也影响其能带结构.另外,585双空位缺陷对能隙较小的锯齿型石墨纳米带输运性质的影响较大,而对能隙较大的锯齿型石墨纳米带影响很小,缺陷取向并不显著影响纳米带的输运性质. 关键词： 石墨纳米带 585空位缺陷 电子结构 输运性质     

H2O在SrTiO3-(001)TiO2表面上吸附和解离的密度泛函理论研究

利用密度泛函理论研究了0.25单层(ML),0.5ML,0.75ML和1ML吸附率下H2O在SrTiO3-(001)TiO2表面上的吸附行为.比较了不同吸附率下分子吸附和解离吸附的稳定性,利用微动弹性带(nudged elastic band)方法计算了H2O的解离势垒.结果表明:在低吸附率(0.25ML和0.5ML)时,H2O表现为解离吸附;在0.75ML吸附率下,分子吸附和解离吸附同时存在;而在全吸附(吸附率为1ML)时,分子吸附更稳定.基于对H2O分子与表面之间以及H2O分子之间的电荷转移和相互作用的分析,讨论了吸附率对H2O吸附和解离的影响.     

溶剂折射率对β-胡萝卜素拉曼散射截面的影响

以环己烷的1444 cm^-1拉曼线为内标,采用5145 nm激发光分别测量了β-胡萝卜素的C=C双键（1520 cm^-1）和C—C单键（1155 cm^-1）振动模式下在不同折射率溶剂中的拉曼散射截面,结果表明随溶剂的折射率增加β-胡萝卜素在两种振动模式下拉曼散射截面都增加.利用色散力和共振拉曼理论解释了在不同折射率溶剂中β-胡萝卜素散射截面的差异. 关键词： 拉曼散射截面 β-胡萝卜素 色散力 共振拉曼     

双回路紧凑型干式蒸发器的设计

对一种双回路紧凑型干式蒸发器进行了设计,给出了合理、新型的结构布置;对传热性能进行了计算,分析了污垢热阻对传热总热阻的影响。认为双回路紧凑型干式蒸发器实现了结构紧凑、节约空间的目的,随着并联机组应用的增加,该类型的干式蒸发器的应用也将日趋广泛。计算表明,采用高效强化换热管后,污垢热阻的数值将对传热强度构成重要影响,除垢防垢将成为提高传热效果的重要内容。双回路紧凑型干式蒸发器的设计和制造,对加工工艺提出了更高的要求。     

一种新型回转式制冷压缩机的设计

介绍一种新型回转式制冷压缩机,其是结合滚动转子式制冷压缩机和涡旋式制冷压缩机的特点,组合部分制冷压缩机的优点而设计的。所设计的新型制冷压缩机具有零部件少、制造简单、效率高、噪音小、运行平稳、适用功率范围广的特点。目前该制冷压缩机的开发还处于初级阶段,但对于开发有自主知识产权的新型压缩机产品,对于我国压缩机制造水平的提高、压缩机制造企业及制冷空调行业的发展有着重要的意义。     

Emergency response to disaster-struck scale-free network with redundant systems

Disasters cause tremendous damage every year. In this paper, we have specifically studied emergency response to disaster-struck scale-free networks when some nodes in the network have redundant systems. If one node collapses, its redundant system will substitute it to work for a period of time. In the first part, according to the network structure, several redundant strategies have been formulated, and then our studies focused on their effectiveness by means of simulation. Results show that the strategy based on total degrees is the most effective one. However, many nodes still collapse in the end if redundant systems do not have sufficient capability, so emergency responses are necessary. Several emergent strategies controlling the distribution of external resources have been proposed in the second part. The effectiveness of those emergent strategies are then studied from three aspects, such as the effect of strategies on spreading processes, minimum sufficient quantities of external resources and determination of the most appropriate emergent strategy. In addition, the effects of redundant intensity on these aspects have been discussed as well.